Organolithiums: Selectivity for Synthesis

Especially detailed accounts are reserved for aspects of diastereo- and enantio-controlled organolithium synthesis and reactions, for example, using sparteine as a chiral ligand.

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For example the Shapiro reaction, a very useful process for alkenyllithium synthesis, eventually finds a home in chapter 8, which bears the title Organolithium Rearrangements .

Organolithiums Vol 23 Selectivity For Synthesis

For example, aspects of organolithium synthesis by cleavage of a CS bond can be found in each of chapters 2–5, depending on the particular sulfur function and mode of reaction involved.