Organic chemistry: “Reactions of and ”. formation through attack of secondary amines on and ; as ; of ; synthesis problems involving . condensation; crossed condensation; condensation. condensation; condensation; crossed condensation; condensation as a route to . ester synthesis; ester synthesis. Michael addition; Michael acceptors; Michael donors
Organic chemistry: “”. How to make and alkyl (). Reactions of and alkyl (with solvents, and , and ). Synthesis problems—using radical , E2, SN2, oxidation (PCC), and for synthesis. The “” technique for solving synthesis problems.
Organic chemistry: “ aromatic substitution problems”
Organic chemistry: “Amino acid and polypeptide synthesis”. Amino acid synthesis--Gabriel synthesis; synthesis. degradation. Polypeptide synthesis-- () and () amino-protecting groups; protection of the terminus via ester formation; DCC () -activating reagent. An example of calculating and charge at a specific pH for a long polypeptide
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Organic chemistry: “Ethers”. Ethers. Williamson ether synthesis (preparation of ethers via SN2); . Digression on how to remember the -Lowry and Lewis definitions of acids and bases. Cleavage of ethers with (HX). Effect of positive formal charges on reactivity. Effect of acid or base on reactivity.
Organic Chemistry Synthesis Problems With Answers
Organic chemistry: “”. of alcohols (PBr3, SOCl2). (, alkyl , ). Using the technique to solve synthesis problems involving (Gilman reagents).
Organic Chemistry Study Guide - 1st Edition
Organic chemistry: “Alcohols, oxidation, and reduction”. Oxidation of alcohols (PCC). Reduction of and with to form alcohols. Synthesis with . Reduction of with NaBH4 or LiAlH4 to form alcohols.
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Organic chemistry: “Introduction to Grignard reagents”. Reaction of Grignard reagents as bases with solvents. Reaction of as with and . Introduction to synthesis with .
Organic Chemistry Synthesis Practice Problems Answers
Chemistry: “Bohr model problems”. Problems involving the Bohr model of electronic transitions for the hydrogen atom and other one-electron species
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Paul Dochety's blog at was a massive inspiration to me in my early days as a blogger, showing me that there was enough of a synthetic organic chemistry community online to make writing seemingly very esoteric posts on a small, specialised sub-field rewarding and worthwhile. A couple of years ago, Paul moved away from the online community, but continued his excellent monthly column for the RSC's (think British C&EN, if you're not familiar with it). However, his tenure there has recently also , and to try to fill the organic-shaped hole in its opinion pages the RSC has commisioned a new column – Organic Matter. As you've probably , authorship will be shared between myself, Karl Collins (of ) and the legendary Chemjobber (anyone who needs a should really rethink their blog-reading priorities).